From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks (2024)

Islamoglu, T., Ray, D., Li, P., Majewski, M. B., Akpinar, I., Zhang, X., Cramer, C. J., Gagliardi, L. (2018). From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks. Inorganic chemistry, 57(21), 13246-13251. https://doi.org/10.1021/acs.inorgchem.8b01748

Islamoglu, Timur ; Ray, Debmalya ; Li, Peng et al. / From Transition Metals to Lanthanides to Actinides : Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks. In: Inorganic chemistry. 2018 ; Vol. 57, No. 21. pp. 13246-13251.

@article{f6a1fad9b130411dace7fc952a4e99ca,

title = "From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks",

abstract = "Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.",

author = "Timur Islamoglu and Debmalya Ray and Peng Li and Majewski, {Marek B.} and Isil Akpinar and Xuan Zhang and Cramer, {Christopher J.} and Laura Gagliardi and Farha, {Omar K.}",

note = "Funding Information: O.K.F. acknowledges the support from the U.S. Department of Energy, National Nuclear Security Administration, under Award Number DE-NA0003763 and Northwestern University for the experimental work. The theoretical work was supported as part of the Inorganometallic Catalyst Design Center, an EFRC funded by the DOE, Office of Basic Energy Sciences (DE-SC0012702). The computations were performed at the Minnesota Supercomputing Institute. Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = nov,

day = "5",

doi = "10.1021/acs.inorgchem.8b01748",

language = "English (US)",

volume = "57",

pages = "13246--13251",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "21",

}

Islamoglu, T, Ray, D, Li, P, Majewski, MB, Akpinar, I, Zhang, X, Cramer, CJ, Gagliardi, L 2018, 'From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks', Inorganic chemistry, vol. 57, no. 21, pp. 13246-13251. https://doi.org/10.1021/acs.inorgchem.8b01748

From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks. / Islamoglu, Timur; Ray, Debmalya; Li, Peng et al.
In: Inorganic chemistry, Vol. 57, No. 21, 05.11.2018, p. 13246-13251.

Research output: Contribution to journal › Article › peer-review

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T1 - From Transition Metals to Lanthanides to Actinides

T2 - Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks

AU - Islamoglu, Timur

AU - Ray, Debmalya

AU - Li, Peng

AU - Majewski, Marek B.

AU - Akpinar, Isil

AU - Zhang, Xuan

AU - Cramer, Christopher J.

AU - Gagliardi, Laura

AU - Farha, Omar K.

N1 - Funding Information:O.K.F. acknowledges the support from the U.S. Department of Energy, National Nuclear Security Administration, under Award Number DE-NA0003763 and Northwestern University for the experimental work. The theoretical work was supported as part of the Inorganometallic Catalyst Design Center, an EFRC funded by the DOE, Office of Basic Energy Sciences (DE-SC0012702). The computations were performed at the Minnesota Supercomputing Institute.Publisher Copyright:Copyright © 2018 American Chemical Society.

PY - 2018/11/5

Y1 - 2018/11/5

N2 - Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

AB - Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

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Islamoglu T, Ray D, Li P, Majewski MB, Akpinar I, Zhang X et al. From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks. Inorganic chemistry. 2018 Nov 5;57(21):13246-13251. doi: 10.1021/acs.inorgchem.8b01748